I would very much doubt that pH by itself determines the "safety" of the ink. Safety to what? To the nib or to the paper?
The only scientific reason that low pH is "bad" is that it may react with the paper as it dries. For example Pelikan Royal Blue tends to fade on some paper. I understand that paper needs to be alkaline for preservation reasons but that could spell "trouble" for low PH inks.
I have also heard that it is not the pH by itself that is important but its stability. If it drifts, the viscosity may change - for this they add "buffing" compounds to the ink.
In any event, I do not claim to be a chemist and sometimes half-knowledge is worse than lack of knowledge. So I would vey much like to hear a "true" chemist to explain all these to us.
Till then here some interesting links for inks
Glenn Markus ink pageRumors and BS about Ink from G. Clark (Inksampler)