QUOTE(Poetman @ Jan 18 2008, 01:30 PM) [snapback]482705[/snapback]
In general were most older inks with iron? or waterproof? or not?
Most were not waterproof. Some made that clear in the label, for example, "washable blue." If the label said "permanent" they were more water resistant, but normally not fully waterproof. The principal type of "archival" ink normally was based on iron gall, which is very acidic and some would argue could corrode metal parts of the pen (aside from gold, of course). Whether the iron gall inks would eventually "eat" the paper would depend upon other factors, such as whether the paper was buffered (as many archival papers are), and whether the page got moist.
For many uses, such as school work, a washable ink was considered highly desirable. Stains of washable ink on clothing would generally wash right out.