Why are CS caps so susceptible to this degradation?

It looks that the cap is not a solid piece but a thin layer on top of a substrate that degrades in contact with ink.
The failure typically occurs at the end of the inner cap where ink is collected.
Most probably the inned plastic absorbes the water and through many cycles of wetting and drying it crambles.
You can see it in some pen in its initial state as a grove in the cap. Then in worse cases the cap breaks completely revealing the degraded inner plastic.
Any ideas how to prevent it? Maybe a coating of shellac? Any other ideas?

